Ryan:
Timeless gloss and Hahnemuhle protective spray are totally different kind of products and technique of spraying totally different.
Using the Timeless, you don't want to put on a heavy coat--more of a dusting type application, or you will be totally dissappointed. It's all in the technique of application. You will need to spend some time experimenting.
Regarding exhaust fans, unless you are doing lots and lots of spraying, I would not worry about it. You should cover anything in the room to protect it from the overspray. The Hahnemuhle spray of course is a solvent product, and of course potentially explosive if you get enough concentration in the room and have a point of ignition.