Update:
After an extended ticket correspondence with Support, it is now accepted that, at least with my setup (Windows 10 Pro x64 / C1 Pro), there is a bug in the Colour Editor.
This is after testing it with files from three different cameras. Canon 1Ds Mklll, 5D Mk IV and Sony RX100; all in RAW mode.
With a file in the browser that has NO edits applied to it, if I click on the image with the CE eye-dropper tool, the RGB readings in the CE and top of the screen are identical. Also, the colour swatch in the CE is the same as the colour in the image.
If I make a change to, say, Exposure and then take a sample, the RGB readings in both readouts remain identical.
However, if I make a change to Levels and take a sample, the RGB in the CE is about 20 points higher than the top of the screen readout.
If I make a change to a LUMA curve and take a sample, the RGB in the CE is about 20 points lower than the top of the screen readout.
This is the same pattern for all three cameras.
Editing changes introduce discrepancies in RGB readings, which I'm assuming shouldn't be the case. Support seem to agree with me.
They are not sure when this bug will be fixed.
D.