Your Canon 5D2 captures RAW reds just fine. In fact, most people have problems with reds being too dominant, over saturated. If you are seeing weak, off-color, under saturated reds then there is a problem in your workflow - camera profiles, monitor profiles, image adjustments.
You would be best served by posting a raw file of one of your sunsets. Others would process that and show you different versions. That would help you track down the issue. Otherwise, all you have is speculation.
Specifically, bring a sunset image into LR, apply your adjustments and profile, export that as a DNG and upload to somewhere like Dropbox. That raw DNG would have all your adjustments AND your profile embedded, allowing others to see exactly what you are doing. If you upload just the original CR2 raw, we can't see your adjustments or profiles.