I do believe there is more separation between the girl and the buildings but as I just discovered oh so badly, the internet compression of blacks in jpegs is just terrible. You might want to try this method rather than dodge and burn tools which are so pixel disruptive.
Use your quick select tool and select the whole of the girl, sans the left and right edges of her arms. make a Curves adjustment layer and change the blend mode to "Screen." You can do several things with this mask. You can feather the selection, lower the opacity, or paint on the mask to darken or lighten certain areas. I use this method frequently.
I did this on your image but as you can see, the internet still wants to clip the blacks to the point of oblivion.