Really RG… it's not a matter of colour accuracy, it's more a matter of having to work with interpolated colour, you see, a painter, when he works with a colour, he does so with respect to lighting... this is very different than judging the colour accuracy on a colour chart that you only have one tone of it…. In other words, with interpolated colour, you may achieve accuracy in the mid tones, but the same colour may "crack" as the painter paints it lighter and darker with respect to the paint's lighting.
@ T.Dascalos (Others, please, excuse a very brief diversion from regular programing.)
You put your finger on it. The mid tones are almost always on the mark, but the lighter areas fall apart, or as you said "crack". My 5D used to blow the highlights without a possibility of successful recovery; D800 does better at preserving or recovering light areas, but slightly warm highlights shift into neon yellow/orange, e.g. When these color shifts are globally corrected, the rest if the image suffers. And correcting color locally is doable, but labor intensive. If post processing of repro work takes longer than to complete the actual painting in the first place, one is encouraged to consider other options. Much can be said about the difficulty portraying some colors in nature with artists' pigments or photographic media, the challenges of painting, capturing light, how light is reflected from paintings vs prints, etc., etc.
I have rented a H4D-40 when it was first released and on the calibrated monitor the images were clearly closer to the original than the files take with 5DII. However, those differences were minimized in the final product - the print. Yes, even when that print was made by a high end art repro outfit. Fast forward three years later, I am revisiting the issue in view of technological advances and .... more affordable pre-owned
MFDB possibilities.
Back to regularly scheduled programing.