samueljohnchia, I believe that exact matching of each color patch is possible, but first we must look at most fundamental elements in color information record and conversion, without blend in tone curve, LUT and such kind of after processing
In my understanding, if lighting is D65 and tone curve is linear, a calibrated camera color checker shot will always show the exactly number as reference value, if the sensor is enough good
Last time I discovered that DNGPE don't change the matrix, and I don't like LUT (it will make large area of gradualy changed color unnatural), if a good sensor act very close to human eye's cone spectral response, a single matrix should fix all the matching point on the gamut. In reality the sensor can not be perfect, so some kind of error has to be tolerated, but anyway without a LUT most of the transfer between colors will be gradual and natural
My past experience showed that if the sensor have a high quality, with a very good matrix, you can almost get all the color patches correct: Blue/Green/Red patch can be fixed 100% accurate, and the rest of them might have some error, and you adjust the matrix to reduce the error on other patches and increase the error on B/G/R patch until all of them fall into similar error level
I just picked up the CC24 and did some further testing. To my surprise, under a noon sunlight and 360 degree blue sky at northern europe (Standard definition of D65), the color temp indicated by camera shows 5800K, and the CC shot in ACR get a white balance of 5500K if I pick the second grey patch to do a white balance
So I get some difficulty: It seems that the daylight (sunlight + bluesky) is far from Illuminate D65, it is possible that D65 is a mixture of shadow (9000K) and direct sunlight (5000K), so I can not get a D65 lighting casted on the color checker. Maybe it is still May, I will try it in mid-summer to see if there are some difference, but since the sunlight is already very strong, I doubt even in June it will not be 6500K, maximum 5900K