After a lot of thinking over the weekend I did two test prints this morning and I've reached a point where I'm happy with the quality of the print.
I used these settings to deviate from the defaults the driver applies when Premium Luster 260 is selected:
Print quality: 2880x1440dpi
High speed: off
Color density: -10%
Drying time: 50 (longest)
Paper thickness: 4
Platen Gap: Wider
It's a super-slow print, and it's likely I did not need such a long drying time. But I figured rather be safe than sorry. The regions I was having trouble with are now smooth.
The attachments show my first test from Friday, with the 'ink-pooling' trouble, and the third test I ran. I did not scan the second test as the only difference between second and third is the Color Density adjustment. I dropped it from 0% to 10% for the third. On the second I was getting a weird gloss differential on the darkest parts that look to me like too much ink. The color density adjustment sorted this out.
This stuff scans really dark, so the images have been brightened to show the issues I've written about.