I haven't had an issue with yellowing especially in just a couple years, but I have to imagine everything that is varnish (even glass) changes with time. I suppose this would be more noticeable with a photo with lots of white. And naturally sunlight will speed the process up. I don't care about what it will look like in 200 years. Can't argue if you want basically non-yellowing use automotive acrylic urethane. You can't spray the acrylic urethanes without a very good respirator and preferably a fresh air unit or you will simply die. Supposedly the automotive refinishing industry is going through some drastic changes, they aren't going to allow just anybody to walk into their local body shop supply store and buy coatings (they aren't supposed to now), you will need to be licensed and the biggest change coming is all finishes eventually will be water based, YUK
. I guess I'm going to have to start experimenting because everything will eventually be water based. I don't even use water based urethanes on hardwood floors yet. There are finishes you can't even buy in this country (polyesters, extremely high gloss) and that's why all products come from across the globe. It will be very interesting to see where it all goes from here, but while it's available have fun! I only use lacquers to seal, final finish is much too thick for lacquer, it'll crack over time.
Definitely have to allow the adhesive to dry and generally 24-48 hours works, but as always, do as I do, read the darn directions!
You have to remember, I have to assume that if you want your "works of art" to last 10,000 years or longer, I doubt this is the right process for you. I've had "experts" tell me hardboard and MDF aren't "archival" and I said neither is wood, but there's a lot of paintings from the old masters painted on wood, the Mona Lisa is one. I don't know what the life expectancy of MDF or hardboard is, but it's probably much greater than the glue and or finish and I really don't know how long they will last.