Something strange happened when doing some B&W work. I took a landscape with dramatic sky from raw into Photoshop as 16bit Prophoto. I added a B&W adjustment layer, and lowered the Blue & Cyans to make the blue sky very dark. Then I noticed some blue/green tint in some areas. Actually, only in areas with RGB values between 26 and 31.
The tint is obvious on screen, but the info pallet shows no tint, all RGB values are equal. So I do a print screen and paste that into a new document. On that image the tint is still obvious, and the info pallet shows it. RGB values like 25-34-34. In all samples I took, Green and Blue are equal, but 5 to 10 points greater than Red. So, I'm starting to think my monitor is wacky.
But I do it all again in Adobe98 instead of Prophoto, and there is no problem. No tints anywhere, everything perfectly neutral. I go back to the Prophoto version and convert it to Adobe98. Volia, the tints disappear! But, the whole image gets darker in tone. The average goes from 97 to 84 on the B&W version, while the color layer looks unchanged. I convert the image back and forth between Prophoto and Adobe98 several times. The tint always appears in ProPhoto, never in Adobe 98.
Next I flattened the ProPhoto version, thinking something is happening in the conversion, but the tint stays in Prophoto and goes in Adobe98. So, I'm stumped. Anybody got an idea what's going on here?