Edmund, the display is indeed an LCD - it's the Eizo CE210W, definitely not a cheap monitor, marketed as geared towards colour accuracy: one step down from the CG range. Approximately US$1,200 worth.
Before calibration I ensured the screen and power savers were off, and it warmed up for about four hours whilst I was working at my day job.
This is a new monitor, and a new graphics card (Radeon X1600PRO dual DVI). I had 2x 20" Apple Cinema Displays before on an Asus card, one of the monitors died. I de-installed the PowerStrip drivers I created for the ACDs, I did not use WinACD. I also de-installed all the previous graphics card drivers before loading my new card, and there have never been any other monitors on this system - no possibility for rougue monitor drivers. I re-added the second, non-dead ACD monitor and it calibrated as well as it did before.
There are no other profile loaders in my PC, I can verify that the correct profile is loaded through the 'Color' WinXP control panel. I have no other monitor profiles loaded except the ones I create. Adobe Monitor Gamma (or whatever it's called) has not been on my system ever - that's not interfering.
I demo-tested ColorEyes before I bought BasICColor, I don't think I can demo it again. I'm loath to buy another calibration software unless I can be sure that it will sort out my issue. One thing in favour of ColorEyes was that I found Jack Bingham to be very helpful and responsive; I doubt I'll get anywhere with BasICColor over the weekend...