For a low key end result, assuming I am shooting raw, is it appropriate to expose to the right, and then lower the exposure in post?
Hi,
By simply using the exposure meter in the camera for a low contrast scene, you are likely to expose the highlights in such a way that the Raw date still has a lot of headroom before it starts clipping. Therefore it will improve the S/N ratio of the entire range of image data if you allow more photons to expose the image, by 'overexposing' relative to the regularly metered exposure. The scene contrast determines how much 'hotter' the exposure can be, still without clipping the highlights. A tool like Rawdigger will allow to fine tune how far you can increase exposure before clipping the highlights. It is not impossible, but hard to do this with the camera generated histogram which is based on the image's JPEG thumbnail. One way you could get close to optimal, is by (spot-)measuring with the camera meter the highlights that should remain unclipped, and add approx. 3 stops of exposure bias.
Once you have the optimally exposed image (which will have an image thumbnail that's too bright) you reduce the brightness of the exposed image to normal levels, with the controls for that (often labeled "Exposure", which is a bit of a misnomer) in your Raw converter. The resulting imagedata should have a better Signal to Noise ratio, leading to cleaner and usually more robust imagedata for postprocessing. Do note that some Raw converters are limited in the number of equivalent Stops that the apparent exposure can be reduced. Also, some Raw converters apply a tone curve, assuming an average exposed image. Pulling "exposure" in postprocessing, works best with a relatively 'linear' tonecurve response.
Cheers,
Bart