You can try it but, like I said, I think if you expose it properly for the center and then try to lift the edges it won't be that good. Film has such a limited dynamic range that the corners will not look very good at all. Transparency film has a dynamic range of maybe 5 stops so if you are underexposed in the corners by two stops due to exposing properly for the center, after raising that in post processing, you are only left with a grainy 3 stop dynamic range area of the photo. Depending on the subject, that could look pretty bad. On the other hand if you take one shot that is exposed properly for the center and then another properly exposed for the corners and build a smooth blending mask in Photoshop you can get a really great result.