I don't see a problem here. One takes a shot of a sunset presumably because one finds the moment impressive, unusual, wondrous, dazzling, attention-grabbing, spectacular, awe inspiring and so on.
As one processes the image, one hopes to recreate that emotional experience which inspired one to take the shot in the first instance. If one errs on the side of excessive vibrancy, so what!
If the image is for scientific purposes, or for ordinary practical purposes such as displaying the various shades of Dulux paint for sale in the hardware shop, then accuracy is required because customers might complain if the color of the paint in the tin is noticeably different from the advertised shade in the brochure.
I like the attached sunset shot because the cloud formation looks a bit like a dragon. if I were to make a print of this image, I'd title it, "The Fiery Dragon".
Anyone who infringes my copyright on this image will be eaten by the fiery dragon, so be warned.