I shot architecture for several years with a Valeo 22wi and a Linhof Techno and a Schneider Digitar 5.6/35mm. The results were very good, but handling was pretty tedious because of the need to tether the back if you wanted live view or image reviews. I had a Macbook Air 11" mounted to the tripod via a Manfrotto Magic Arm and a little platform. The good thing about the Valeo, compared to more recent backs, is that it can be powered from the Macbook via the Tunderbolt-Firewire adapter, no need for an external power supply via a Firewire hub. The downside is that you are bound to the quite ancient Leaf Capture for live view (but live view works really well with the Valeo and LC!).
When browsing through ebay and the Luminous Landscape and getDpi for sale forums recently, I saw quite a lot of offers for relatively cheap Cambo Wides and Horseman SW-Ds, which seem to be good cameras for architecture (both really designed for use with wide angle lenses and rise/fall/shift only, no tilt without special add-ons). I have no personal experience with those cameras, but it surely would be a huge step up from the DSLR, if you get a Schneider or Rodenstock 35mm or something similar.
hope that information is useful for you,
best,
Gebhard