So I have my new nas setup at the house. Can anyone give me an idea of what I need to do to have both my computers use this nas?
What speed? Gigabit? Using a network switch and managed network or a router? As Wayne says, yes you can do it to a point...but do you really want to?
Lightroom is a single user application so while you CAN place the images on the network drive and access the images from multiple computers, you CAN'T have the LR catalog on the server and access it from multiple computers. What that means is if you really want to access the same images from the same catalog from multiple computers, you're gonna have to figure out a way of moving that catalog back and forth to the 2 computers. Last update wins (the older catalog looses).
Really, what you think you want to do, you really don't want to do...(and can't).
And if you aren't running a switch managed gig network, you'll regret going down this rabbit hole–seriously it will be painful with anything other than a really fast network connection (meaning forget WiFi of any flavor).
You would be better off picking one of the computers to use as your "Lightroom computer" and give it the local fast connected drives (eSATA or at a minimum USB 3 or Firewire 800) and simply use the NAS as a backup and don't even worry about trying to connect to the images over your LAN. As Wayne indicates, it's useful to save out the .XMP settings metadata but that will not keep a LR catalog in sync.
I think you need to re-think what you think you want to do...