Rob,
Those girls do not need Hans or 300mm to look amazing.
Given how skinny models are, telephoto flattening (and fattening) of their faces can only do them a favor.
100mm is considered the most natural for head and shoulders portraits, especially if hands are involved. By most natural, it is meant as the proportion of hands, nose, etc. size to face. Shorter than that, say 50mm, makes hands larger than face, and the nose more prominent, for instance. But what do I know, I only read about it, with visual examples, in Modern/Popular Photography, penned by Herbert Kepler, if I am not mistaken.
On a personal note, when I shoot my daughter full-face at 200-300mm, she wants to shoot me: it makes her face fat and flat.