My very limited understanding of how batteries work is that when they get older the internal resistance increases. When resistance becomes so great to not allow a sufficient flow of electrons and deliver the promised voltage, the battery is ready to be recycled. Does this internal resistance present a problem when refreshing the battery, or does the discharge cycle not even see this effect?
We have some older Canon Ni-MH batteries, for our 1Ds Mark II's, that I suspect are ready for the recycle bin...they don't hold a charge for nearly the number of exposures they use to... which is not surprising, but they seem to take an inordinate amount of time to refresh when I do refresh and recharge them. Anyone have any insights on this?
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I'm not an expert either, but I do use NIMH AA batteries quite a bit. Not the same size that you use in your 1Ds Mark II, but NIMH is NIMH.
What I've found is that once the batteries no longer hold the same charge that they originally did, or after a long period of non-use, they need to be "re-conditioned".
I use Powerex batteries and chargers which allow for this by fully discharging the batteries and recharging them at the push of a button. At times, it's neccessary to go through 2 or 3 cycles to attain a full charge, but they do charge fully after that.
There does come a point when nothing will help. That's when it's time to recycle the batteries and buy new ones.
I'm not sure if Canon chargers work the same way as Powerex. If they do, then you already know all this.