Nice shots, both, by the way. In looking at the two does, the first appears to be a yearling while the second is older in my estimation. That could account for the difference in behavior. I've seen a lot of yearling deer that seem to know they should be afraid of human scent, but just don't quite get it yet. After another year, they get it. Of course all of their normal behavior is different if they live in a protected area and are habituated to the presence of humans. Just look at the elk wandering the streets of Estes Park for example.