Aluminum and stainless steel panels are more rigid than aluminum composite panels like Dibond, and have less tendency to warp with temperature swings. At the same thickness they are much heavier than Dibond. The edges look monolithic on solid aluminum panels, versus the exposed laminate structure on Dibond. Pure aluminum panels are a PITA to cut and edge-sand in your shop, Dibond is relatively easy. Solid aluminum is very expensive these days.
Can't find the shot of Anne Liebovitz carrying the 2025-T6 aluminum panel under her arm, but if I could you would be darned sure to see it here. There are many grades of aluminum panels, the common 6061 panels are mushy and unpleasant to work with, OTOH 2025 aluminum machines very crisp and yields super defined, weapon-like edges. Or maybe she had a 7075 panel, same deal.
The biggest difference is that except for some very premium suppliers, it is difficult to get aluminum panels that are consistently cosmetically appropriate for presentation purposes, and "features" like brushing and such will come with a high degree of variation over time. Dibond is primarily for refined fabrication applications and signage, it tends to reach you in a good and consistent condition and the brushed versions always look the same. And both types of panels are a damned nuisance to handle and store while they are in your shop, they tend to brutalize everything they come in contact with including you, those corners in particular are nasty.