Khurram,
You don't specify a price range, but if you have plenty of money, The Ventana Inn
and the Post Ranch are two of the best hotels in the United States - a quick look at the Ventana Web site shows a two night photography package deal for only $1500. (and it's the cheaper of the two.) The River Inn is the one that rabidog refers too, although with the current rain situation, the wooden chairs aren't in the creek, they are either in the ocean or in the barn. It is 26 miles from Carmel to Big Sur (the Big Sur Marathon takes the whole route.) There are literally dozens of hotels in Carmel, and more in Monterey, which is another 5 miles north. Photo opportunities exist for the whole route, so staying in Carmel doesn't really put you 26 miles form the action.
Alan