In my experience with smaller iPF series printers, gray is generally by far the first to go regardless of your mono/color print mix. Light gray, PM, PC, PK/MK, Y the next. R, G, and B last the longest by a good margin.
No problem with removing carts for weighing, etc. What doesn't work is adding ink to carts by syringe once the "empty cart" message is shown - Ive tried it as an emergency measure, harvesting about 25 ml from used Gray carts.
Pete