You must select the portion of the face you want to filp. As I said, that's the difficult part. So select the left side of the face, just use a square marquee tool for the time being.
Copy or better, Command/Control J (copy to a new layer).
You can simply use the Flip command I originally provided. Move that into the new position.
IF you need to do more than a simple flip, you need the options in Free Transform, you can do that too. After you have the copied part of the face, call up Free Transform (Command/Control T). If you select the contextual menu (Control Click), you'll see various options including Flip Horizontally. After the flip, you can continue to move the Free Transformed selection into position, scale, skew, etc.