What film would be recommended for this kind of work ? I've heard that long-ish exposures tend to introduce color shifts in some films.
Astrophotographers have always had different criteria for film selection to "regular" photographers.
To pick up faint deep-sky detail, within a reasonable length of time, one needs very low reciprocity failure, at least moderate (ISO 200-400) box ISO rating, perhaps 1-2 stops of pushability without hitting golfball grain, and ideally, extended red sensitivity for nebulae. Kodak E200 was all of that. That film is gone.
Also gone are the great Kodak Tech Pan (needed hypersensitisation beforehand), Kodak E100S and the not quite as good E100G, Fuji Provia 400F, Fuji Astia 100F, the original Fuji Super G, Fuji Superia 100CN, the original Agfa Optima 400, Agfa 200RS and 1000RS, Konica Centuria 400 and 800, and a slew of Kodak ISO 400-1000 print films from the late '90s/early 2000s.
What we are left with doesn't really fill the gaps. In many cases, the same film was "improved" but the improved daytime performance was a setback for astro performance; a loss of red sensitivity or an increase in reciprocity failure/colour shift.
So. The remaining Fuji slide films are winners on low reciprocity failure, with modest colour shifts (Provia is better than Velvia), but no extended red sensitivity. They are a good choice for star-trails. From Kodak, Ektar 100 and Portra 400 have good grain and green-blue responses, but a colour shift which really hits their red response. In B&W, Fuji Acros has amazingly low reciprocity failure, but low base speed and poor red sensitivity. Ilford Delta 3200 has raw box speed, but poor reciprocity and grain and it is not competitive with the signal to noise of a DSLR at the same ISO 3200 setting.
Have a look at the work of James Cormier aka "Nightfly" on Flickr, Cloud Nights, Fluidr, nightflyphotography.blogspot. He has been testing and shooting a lot of different films for astrophotography with a Pentax 67 kit.
Ray