“Archival- a term often used to imply that a material will be stable over time. The term has neither a recognized standard definition nor a quantifiable method for verification.” The Image Permanence Institute, a department of RIT’s College of Imaging Arts & Sciences, (
http://www.archivaladvisor.org/shtml/glossary.shtml)
The American National Standards Institute (ANSI) agrees:
“(Archival media is) material that can be expected to retain information forever, so that such information can be retrieved without significant loss when properly stored. However, there is no such material and it is not a term to be used in American National Standard material or system specifications.” The American National Standards Institute (ANSI/AIIM TR21998, “Glossary of Document Technologies,” Association for Information and Image Management International, Silver Spring, MD.)
As mentioned the term archival gets thrown around a lot but doesn't have a standard meaning.
To your original question regarding RC paper, I'm not sure about whether cotton or other fiber is used, although some report the paper base itself is a cotton fiber base. I personally believe this is irrelevant, since RC paper is made by coating both sides with a polyethylene coating. The origination of the paper was wet photo processing and was a significant step in the evolution of photograph as it made it much easer and faster to process photo papers without the paper absorbing any chemicals, meaning must less washing and much faster drying. Inkjet RC papers use basically the same RC coated paper then apply an inkjet receptor coats instead of photo sensitive emulsions. The goal early on to gain acceptance in the photo side of things for inkjet companies was to duplicate the look and feel of traditional photographic papers.
So RC paper really isn't new, it's been around for 60 or 70 years (I can't find when it was first introduced). Inkjet RC papers should perform the same as chemically based photo papers, and perhaps better since there is no penetration of any chemicals into the edge of the paper.
The issue with these papers isn't with the paper content, because the polyethylene coatings will break down before the paper, and that's the surface the ink is on. I do not believe these papers will last as long, although certainly 100 years is believable. We have photographs on RC paper that have been around many decades, and the colors may not be great the paper has held up pretty good. But I don't think there is anyway RC papers will last as long as well made non-RC papers.