This thread might be of interest to you.
To answer your question directly (please keep in mind I have no direct experience with the Mac version of Lightroom other than casual use):
Lightroom does not directly support the ability to task your GPU for other than pure rendering to your screen(s). CS4/5/6 does and so do other programs, but so far not LR.
With that said, there is 'some' benefit to be gained with a faster video card depending on what you have now as a starting point and the resolution and number of screens you're driving. And this 'some' will be restricted to very specific parts of your work flow. Go through the thread I linked and review the pertinent data.
As you go through this thread you'll also get an idea of how to evaluate the rest of your system and how to think about performance, bottlenecks, and work flow.
After, ask your questions.