Printing B&W through the color setting(as opposed to ABW or something like QTR) uses all the inks. The Epson inks use magenta to help get a neutral BLK, but it ends up giving it a green cast and your grays end up with a slight red(magenta)hue. As Alan has pointed out, using the ABW inside the printer driver doesn't use as much of the color inks to get neutrality, and relies more on the use of the the 3 BLKS. Another useful program is the QuadTone Rip(QTR).