You're using the Color Editor and you've checked the "view selected color" box, but this is a VIEW of the image only (to make is easy to identify which colors are included in the color patch you've selected). Uncheck that box, invert your selection (one of the icons towards the bottom of the color editor), and then add -100 saturation.
If you live in the US you'd be well served to attend one of our Capture One Workshops. You missed the boat on most of the cities but we still have a few left:http://www.captureintegration.com/our-company/upcoming-events/
Doug Peterson (e-mail Me)
Head of Technical Services, Capture Integration
Phase One Partner of the Year
Leaf, Leica, Cambo, Arca Swiss, Canon, Apple, Profoto, Broncolor, Eizo & More
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