For images like this - sunset in the frame - the harsh transitions are always a problem. Having tried several raw processing options on similar images, Raw Developer is far and away the best software I've seen, producing far smoother transitions from the sun into the sunset than other options. For the images I was working with I used Nikon, Adobe, CaptureOne and RD. The first three were slightly better than the other in the order of the first three listed then a giant leap to the smoothness of the RD gradations. It may take quite a while to understand the myriad of option for highlight rendition in RD, but it's worth the effort for problem images. I'll often process the overall image in C1 and then just the sunset in RD and blend the two.
Obviously it's better to shoot a second or third exposure for blending, but it's not always possible and much more difficult, but not impossible when shooting people.