Just to confirm what Jeff has said (thanks JS), as OpenDirectly's author I see no role for using the plug-in with Photoshop. The original intention was to send raw files directly to other raw converters, but it is designed so that you can choose to send the originals to any kind of 3rd party app. For instance, I use it most often for sending DNGs to geotagging apps such as Geosetter on Windows or HoudahGeo on Mac.
John