I used both Rodenstock and Schneider lenses for 4x5 colour and b&w work for many years, since 1984. As time went on, though I started with Rodenstock, Schneider brought out lense with newer formulations and larger image circles, and I gradually switched. The best Schneider 4x5 lenses were their XL series--90mm XL, 110mmXL, 72mmXL--all fantastic lenses for 4x5 colour. Nevertheless, there are subtle differences between Schneider and Rodenstock in how they transmit colour. For 4x5 work, the Schneider lenses seemed slightly more clinical, but also slightly more "biting" in resolution.
I am using for digital work now four Rodenstock lenses (32mmHR, 40mmHR, 55mm apo, 70mmHR), and two Schneider lenses (47mm and 100mm digitars). The Rodenstock lenses have much more sumptuous colour rendition, especially compared to the 47mm lens which has a large image circle but real colour cast issues about two-thirds of the way out in the image circle (correctable with Phase One or other LCC procedures). The Schneider 100 has better consistent colour but is not quite as sharp as the 40mmHR lens, which is my sharpest lens. The 55mm Rodenstock apo is from a different line of digital lenses, not quite as sharp as the HR lens, but with bigger image circle and excellent colour. The Schneider 100 is slightly sharper than the Rodenstock 55mm which is fine at f/11 and has a very large image circle. The 32mmHR and 70mm HR are not quite as good as the 40mmHR off centre, but colour is excellent. The 32mm and 40mm HR lenses have complex distortion and need a program like Alpa's to correct them.
So to sum up, Rodenstock lenses have a very beautiful rendition of colour. The best in my experience for resolution is the 40mmHR, followed by the 70mmHR, the 32mmHR and the 55mm apo in that order. The Schneider 100 has good colour and good sharpness, at least equal to the 32mm. The Schneider 47mm is very sharp and has a large image circle but colour cast issues that are significant, but far less distortion than the wide angle Rodenstocks and easier to correct. The HR lenses are definitely worth the money, except maybe the 32mm which is overpriced in my opinion, but has no competition for its particular features (flange focal distance) and useability with Dalsa chip backs.