When I switched earlier this year (2010) from film and darkroom photography to digital photography, in addition to giving away all my darkroom equipment, I also gave away my full collection of the late Fred Picker's Zone VI newsletters and instructional videos. So what I'm about to summarize is based entirely on memory.
Fred's modification of Ansel Adams' Zone metering concepts was based on something of a simplification, but I thought very pertinent and effective. Rather than trying to establish certain zone values for a scene, you should instead strive merely(!) to capture what Fred termed (as I recall it) the "Maximum Printable Negative.' That is (obviously) to produce a negative with as full a range of light values from a chosen scene that the limitations of your film would permit. In Fred's view, as I understood it, you don't need to strive to have your negative represent your final aesthetic intent, but rather have the negative contain the maximum information possible to achieve that aesthetic intent in the DARKROOM.
Now, as I see it, the corollary to this for a digital photographer and processor is to similarly achieve a digital capture in the RAW form of a "maximum printable negative.' Then, through a RAW exposure adjustment (and any other adjustment) in the processing software, the photographer's aesthetic intent can better be realized. For most of forum members reading this, the most logical comment will be "Duh!" It IS rather obvious. So, I guess what I'm saying is that, for those photographers (other than point-and-shooters), who employ post-processing software, establish with your camera the broadest range of exposure you can and deal with aesthetic tonality later, in the comfort of your PC.