As I understand it, the chips in ink cartridges do not measure the ink level in the cartridge, but nozzle firings.
Now, there are manufacturing tolerances in the print head, so a droplet which is supposed to be, say, 3 picolitres, might actually be a tiny bit more, or a tiny bit less. Epson has to be somewhat conservative, and assume that the droplets are on the large side of the tolerance, or else someone is going to find that the chip reports that there is still ink left, when there really isn't. There are a lot of nozzles, and a lot of firings, but stochastic averaging makes this method of ink calculation surprisingly accurate.
However, your particular printer might on average produce slightly larger, or slightly smaller droplets than the average printer. So you might find that the amount left in your cartridges when the printer says that they are empty, is consistently more than, or less than the nominal 2%. In your case, it seems that there's more than 14 ml left in your cartridges when the chip thinks that the cartridge is empty.
Assuming that this is true, I would be inclined consider using a chip resetter, and carefully keep using the cartridge until it gets close to being really empty. Having an accurate scale, and knowing the weight of an empty cartridge would seem to be a necessity, as nobody wants their big printer to start aspirating.