I seem to remember that the two new cartridges were only useful in proofing situations and not for general purposes. Perhaps that is what your finding notes. It would be interesting to see long term what the ink usage patterns of the two new cartridges are.
There are thousands of ways to create any individual color when screening and dithering. The main purpose of the two new colors was to allow creation of spot colors, but the firmware still utilizes them on every job.
I've followed print jobs, tracking ink consumption of various colors. We run a mixture of landscapes, portraits work, and art reproduction work on the 7900. we send black and white work to the 11880 so the 7900 prints only color prints and we only use PK, no MK. So far it appears Orange accounts for about 5.7% of the total ink used on average, and green about 3.3%. As comparison, Cyan - 2.3% Yellow 3.8% Light Cyan 6.9% VMagenta 3.2% VLMagenta 10.7%. I was surprised to see orange used more than cyan, but this was about a 30 job stretch and I suppose there were some anomalies in the work printed (such as sunsets etc) which might account for that. I'm going to track it again after Christmas - just a little curious about it.
Blacks are the surprising element here, as PK is about 6.7% but LK is 34.7% and LLK is 22.7%. So about 65% of the ink on the paper is one of the blacks. I've know LLk is the most used color for some time, but didn't realize LLK was used that much.
So I suppose it is possible that the orange ink itself being used in place of other color the 78/9890 printers would use to achieve the same colors could cause some metamerism issues, but still of the opinion it just isn't enough ink to make a difference.