I could not recommend ColorThink 2 either, since it does not do gamut volume calculations. It's the ColorThink Pro version that does gamut calculations, and it also gives 69% (68.9%) as the ratio of sRGB to adobeRGB. These gamut calculations are generally rather crude estimates and are based on the 3D gamut volume as you suggested. When working with such smooth profiles such as these two, though, these estimates should be fairly accurate. Since you bring it up, ColorThink Pro works fine in Windows 7, and we will be working at bringing out a ColorThink 2 (the less expensive) version that will be Win 7 compatible.