I believe that, since the image was not a web image but a download, it was not an sRBG image. I suggest you use Lightroom for processing RAW data and then let Photoshop do the printing. You are likely to get more consistent results that way. Also, as you have speculated, I do not believe changing an image's color space in Photoshop adds any digital color information. I could be wrong now but I don't think so.