The hot-shoe is primarily designed for the SCA3902 interface, however any "central pin" device
should be compatible with one important limitation: The trigger voltage in the SCA3902 interface is 5
V. Due to an over voltage protection circuitry, devices with higher trigger voltage than approx. 6.8 V
will not trigger. The PC-sync socket has a more general interface where this limitation does not apply.
To determine if this is the problem, measure, if possible, the voltage across the hot shoe converter
(central pin and the grounding terminals on the side of the converter), or directly on the flash cable. If
the voltage is more than 6.8 V it will not trigger from the hot-shoe.
I'm not sure what the voltage output is on the Nikon flash.