Digital Rebel XSi Specs:
1lb without battery - body only.
5.1 x 3.9 x 2.4 in
Battery back 1.5 oz.
18-55 zoom lens 6.7 oz.
24.2 Ounces.(just a smidge over 1.5lbs ready to shoot) 18-55mm basic zoom lens.(28-88 35mm equivalent) this comes with it in the typical kit and is a fine lens. Plus it has image stabilization and good optics.
Yes, the Olympus E420 and a few other cameras weigh less, but the lenses are heavier, so it's a wash. I like the Canon as you hardly notice the lens at all - it's almost like a pancake 50mm lens on an old AE-1. Hardly there at less than 7 ounces.
It's a very light and small camera for its type. Not a 3-4lb monster setup like older digital SLRs used to be.
Canon S5 IS camera.(prosumer/larger pocket camera)
15.9 oz.
4.60 x 3.15 x 3.06 in
This of course includes the lens, but as you can see, the Rebel is a very light package. Since she'll need a tripod to take decent composed shots(to get the shots level and the angles perpendicular if nothing else), weight isn't a big deal, IMO, as the average tripod weighs at least 1-2lbs by itself. The body on the Canon is also much better sealed versus dust and gunk than a typical pocket camera.
$650 including the lens. Not a bad deal, IMO. And since that lens is the normal "kit" lens, just take her to any camera store and try it out(them buy online of course to save money).