The polarizer is one of the most essential accessories needed by serious landscape
photographers.
Useful sometimes, but I'd not want to raise it to quite such lofty status - perhaps I'm just not serious enough ;-) :-)
I've often found that (normal lens) vignetting when shifting upwards a lot for buildings works nicely in my favour for darkening skies a bit.
For myself, using the 24 TS-E on my 1Ds3 is one of the times that a filter really is only there to protect the front of the lens - I invariably remove it for any work needing much detail at shift. An old filter I used to have on it did increase vignetting slightly at full shift.
I'm hoping that the word on a new T/S lens later this year from Canon is true, and they are actually going to bring in something new at the wide end.