I highly recommend the DeWalt saws like the most recent 10 and 12" models. They are very well made, but most importantly you can fairly easily fine tune the 45 degree angles, and the registration at those positions is very repeatable. If you want great looking corners without gaps, you must have a very accurate 45 degrees. I use a $900 "Phaedra" miter table with it, although that may seem pricey it is extremely well made and makes cutting moulding about as easy as it gets.
I often cut 5" moulding so I have a 12" DeWalt. There is an issue with those large diameter blades going into oscillation and this can lead to inaccurate cuts. For whatever reason, Freud LU85 series blades almost completely eliminate this oscillation and I am getting great cuts with these blades. "LU85R010" is the 10" blade, "Lu85R012" is the 12 inch.
I have one of the table-top, "Lion Miter" style guillotine miter trimmers. If the blades were 10 times as hard, it would be great. However, the blades on the imports (which is all you can get new at this time) are frankly pretty poor and I rarely get more than a few tens of good cuts. As the blades dull out the joints get extremely poor. Also, those things are wildly dangerous, maybe the scariest tool I have ever used. I really have to recommend against them. And they are for trimming only, you have to rough cut the 45 degree angle with a saw, then take a series of very thin shaves down to size.
The greatest miter cutter of all time is of course the wonderful Morso Chopper. It's a foot operated device with a pair of huge, super quality blades set at perfect 45 degree angles. You get several hundred razor smooth, perfect cuts between sharpenings. Nothing joins better than (most) moulding cut with still-sharp blades. There are a few problem mouldings, such as those wider than about 4", those with angles or curves on the outside edges, those with extremely complex designs on the faces, etc. But for all the mouldings generally regarded as "photographic" it's the perfect thing. About $3100 new with shipping, but you can often find them for less than $1000 used. I use one to supplement my saw, it's my first choice for those mouldings sized and suitable for it. But the saw will cut anything with a little more work.