When converting a color image with a blue sky to Grayscale and then adjusting the blue on the grayscale mix to say -50 or -60 to darken the sky, I notice an enormous gain in noise in the sky. The image was shot at ISO 100 with a ID Mrk2, so has no noticable noise to start with.
Is this normal when adjust the blue grayscale mix? What would cause the excess noise? I have reproduced this with several images with blue skies.
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When you cut the blue channel, the sky is much more dependent on the red channel, which has a very low exposure in the sky, especially deep blue sky.
The quick fix is to mask the sky and blur the red channel, but the more ideal thing to do is to get your exposure up, or use a red filter when you shoot.
Digital cameras are the least sensitive to red light, and in daylight WB, the red channel has the most noise in white/grey subjects, especially in blue subjects.