What do you mean by this: that the gloss surface contributes to more scatter?
Yes, PK's glossy surface, just like window glass, reflects a portion of light hitting it. When it's on a glossy type surface, the surface, even with dimples such as semi-gloss or luster, doesn't deviate more than 15 degrees or so from flat. So reflected light from the PK surface does not extend to the angle where DMax is measured, which is at 45 degrees. Matte surfaces are rough by design and includes much larger angles. As a result, a portion of the PK ink gets positioned to reflect light by 45 degrees and this degrades the DMax. PK inks are really quite black and absorb nearly all light that isn't reflected from their encapsulated, glossy resin coat. This is why DMax is so much better on glossy media.