I don't think the green and orange will help much on the gamut of the matte ink. They don't do anything for matte prints on the 9900. I have read that the yellow on the new 9000 has better lifeproofness, and that may help. The green and orange are mainly for proofing needs as I understand it. In 1 year, with quite a bit of volume for me 25 rolls of 44" canvas and 12 rolls of 24, then paper work, I am still on 1/2 or so of the 150ml orange and green that I installed last Jan. The ink is barely used, I base this on volumes of the others inks I have gone through.
Matte by nature seems to have a much narrower gamut, at least from the profiles I have viewed and created, and by what I see in soft proofing.
Paul C