I have the 150 system for my 14-24 F2.8 and have 'fondled' with the 100 system so can make some related comments.
The 150 filter holder itself is vastly superior to the Lee 150 system. For the 100 system, there's not much in it. The NiSi is cheaper and the all metal build quality is absolutely superb, functionality wise it's about even with the Lee. If I was buying my 100mm kit again, I would go with the NiSi for the holders -based on price and build quality- and filters from whichever supplier suits my needs.
The (150mm) 10 Stop ND behaves VERY similarly to the Lee Big and Little Stoppers. White Balance needs to be at around 10k to get rid of the blue cast. Otherwise, the quality is absolutely superb.
Sadly I don't have any quality images to share as I've a damaged Achilles since I got the system so have only 'tested' the filters in the back garden.